Regioselective one-step synthesis of trans-3,trans-3,trans-3 and e,e,e [60]fullerene tris-adducts directed by a C3-symmetrical cyclotriveratrylene tether

被引:52
作者
Rapenne, G
Crassous, J
Collet, A
Echegoyen, L
Diederich, F
机构
[1] ETH Zentrum, Organ Chem Lab, CH-8092 Zurich, Switzerland
[2] Ecole Normale Super Lyon, UMR 5532, CNRS, Lab Stereochim & Interact Mol, F-69364 Lyon 07, France
[3] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA
关键词
D O I
10.1039/a903226f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first covalent cyclotriveratrylene (CTV)-C-60 adducts were prepared by the tether-directed Bingel reaction, which gave the two C-3-symmetrical trans-3,trans-3,trans-3 and e,e,e tris-adducts with a high degree of regioselectivity.
引用
收藏
页码:1121 / 1122
页数:2
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