The novel magnetic properties of SSSNCCNSSS(M)(2) (M=AsF6, Sb2F11) and the electronic properties of (SSSNCCNSSS+center dot)-S-center dot+

被引：17

作者：

Enright, GD

Morton, JR

Passmore, J

Preston, KF

Thompson, RC

Wood, DJ

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA,ON K1A 0R6,CANADA

[2] UNIV NEW BRUNSWICK,DEPT CHEM,FREDERICTON,NB E3B 6E2,CANADA

[3] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER,BC V6T 1Z1,CANADA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000967

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The variable-temperature magnetic behaviour of the previously reported AsF6- and presently reported Sb2F11-salts of bis(1,2,3,4-trithiazolium), (SSSNCCNSSS+.)-S-.+ (1(2+)), are complex but indicate intermolecular antiferromagnetic interactions and temperature-independent paramagnetism, as well as intramolecular antiferromagnetic coupling leading to a singlet ground state, with a nearly degenerate thermally accessible triplet excited state, which is confirmed by EPR spectroscopy.

引用

页码：967 / 968

页数：2

共 8 条

[1]

ATHERTON NM, 1973, ELECT SPIN RESONANCE, pCH5

[2] THE PREPARATION AND CHARACTERIZATION OF THE PARAMAGNETIC SOLID BIS(1,2,3,4-TRITHIAZOLIUM)BIS(HEXAFLUOROARSENATE) CONTAINING THE DIOXYGEN-LIKE DICATION DIRADICAL .+SSSNCCNSSS+. [J].