Advanced ceramic based on the ternary systems ZrO2(HfO2)-Y2O3-Eu2O3

被引:2
作者
Andrievskaya, ER [1 ]
Red'ko, VP [1 ]
Smirnov, VP [1 ]
Lopato, LM [1 ]
机构
[1] NAS Ukraine, Inst Mat Sci Problems, UA-03142 Kiev, Ukraine
来源
EURO CERAMICS VII, PT 1-3 | 2002年 / 206-2卷
关键词
zirconia; hafnia; yttria; europia; rare-earth oxides; phase equilibria; phase diagrams; liquidus; solidus isothermal sections; fast reactors materials;
D O I
10.4028/www.scientific.net/KEM.206-213.1113
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The ZrO2(HfO2)-Y2O3-Eu2O3 systems were studied in the wide range of temperatures (1250-2800 degreesC) and concentrations by methods of X-ray analysis at 20 degreesC, petrography, DTA in He at temperatures to 2500 degreesC, thermal analysis in air using a solar furnace at temperatures to 3000 degreesC and electron microprobe X-ray analysis. The complete phase diagrams were constructed, The liquidus and solidus projections, crystallization paths for the alloys, isothermal (1250, 1550 degreesC) and polythermal sections are presented. The structure of the boundary binary systems defines the phase equilibria in the ternary system. No ternary compounds were found. Ternary solid solution regions were determined based on constituent oxides and intermediate phases.
引用
收藏
页码:1113 / 1116
页数:4
相关论文
共 10 条
[1]  
Ainscough J.B., 1977, CERAMURG INT, V3, P18, DOI [10.1016/0390-5519(77)90102-8, DOI 10.1016/0390-5519(77)90102-8]
[2]  
Andrievskaya E. R., 1997, Key Engineering Materials, V132-1363, P1782
[3]  
CURTIS CE, 1959, J AM CERAM SOC, V42, P551
[4]   USE OF LANTHANIDE OXIDE NEUTRON ABSORBERS IN PRESSURIZED WATER REACTORS [J].
LEITTEN, CF ;
BEAVER, RJ .
NUCLEAR APPLICATIONS, 1968, 4 (06) :399-&
[5]  
MOORE DA, 1982, J AM CERAM SOC, V65, P414, DOI 10.1111/j.1151-2916.1982.tb10506.x
[6]   SINTERING CHARACTERISTICS OF RARE-EARTH OXIDES [J].
PLOETZ, GL ;
KRYSTYNIAK, CW ;
DUMAS, HE .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1958, 41 (12) :551-554
[7]   SYSTEM HFO2-EU2O3 [J].
SCHEIDECKER, RW ;
WILDER, DR ;
MOELLER, H .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1977, 60 (11-1) :501-504
[8]  
Shevchenko A. V, 1984, IZV AKAD NAUK SSSR N, V20, P1991
[9]   EFFECTS OF TEMPERATURE AND MICROSTRUCTURE ON ELASTIC PROPERTIES OF SELECTED EU2O3-HFO2 COMPOSITIONS [J].
SUCHOMEL, RR ;
HUNTER, O .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1976, 59 (3-4) :149-152
[10]   PHASE-EQUILIBRIA AND ORDERING IN THE SYSTEM ZIRCONIA HAFNIA YTTRIA [J].
TRUBELJA, MF ;
STUBICAN, VS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (08) :662-666