Reactions of bis(pentafluorophenyl)borane with Cp2Ta(=CH2)CH3

被引：40

作者：

Cook, KS

Piers, WE

Rettig, SJ

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Y6, Canada

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 09期

关键词：

D O I：

10.1021/om9900418

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Schrock's methyl methylene complex Cp2Ta(=CH2)CH3 with HB(C6F5)(2) are described. Products arising from attack of the borane at the methylene ligand are isolated; the course of the reaction is dependent on the conditions employed and the equivalency of borane used.

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页码：1575 / 1577

页数：3

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