1-D coordination polymers containing benzenedicarboxylate

被引：50

作者：

Bourne, SA ^{[1
]}

Mondal, A

Zaworotko, MJ

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

CRYSTAL ENGINEERING | 2001年 / 4卷 / 01期

关键词：

inorganic compounds; coordination polymers; crystal structured;

D O I：

10.1016/S1463-0184(01)00007-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation and crystal structures of [Cu(1,3-bdc)(py)(3)](.)11/2 H2O (1), [Cu(1,3-bdc)(py)(3)](.)H2O.CH3OH (2), [Co(1,3-bdc)(py)(3)(H2O)] (3), [Co(1,3-bdc)(py)(3)(CH3OH)](.)H2O (4), [Cu(1,3-bdc)(py)(2) (5), [Co(1,3-bdc)(CH3OH)(4)] (6) and [Ni(1,3-bdc)(CH3OH)(4)] (7) are described (1,3-bdc=1,3-benzenedicarboxylic acid; py=pyridine). 1-4 form straight-chain 1-D coordination polymers with interdigitated pyridyl ligands that are engaged in C-H . . . pi hydrogen bonds. 6 and 7 form similar 1-D polymeric chains, but the smaller methanol ligands allow the bdc groups to stack to form pi . . . pi interactions. 5 forms a rectangular 2-D grid structure with insufficient space for guest inclusion. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：25 / 36

页数：12

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