Spectroscopic characterization of core and shell regions in monolayer protected gold nanoparticles

被引：10

作者：

Compagnini, G ^{[1
]}

Scalisi, AA ^{[1
]}

Puglisi, O ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

来源：

SURFACE SCIENCE | 2006年 / 600卷 / 01期

关键词：

colloid; gold; metal nanoparticles; laser ablation; confinement effects;

D O I：

10.1016/j.susc.2005.10.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report studies on the structure of the metallic core and the alkyl cap layer in monolayer protected gold nanoparticles having sizes down to 1.6 nm. These particles are obtained by laser ablating gold targets in alkane-thiol solutions at different concentrations. The electronic structure of gold core and the vibrational properties of the capping hydrocarbon chains reveal effects connected with the nanosize nature of the particles. (c) 2005 Elsevier B.V. All rights reserved.

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页码：L1 / L5

页数：5

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