Oxidations catalyzed by metallocorroles

被引:152
作者
Gross, Z
Gray, HB [1 ]
机构
[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel
[3] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
关键词
catalytic oxidation; chromium; dioxygen activation; manganese; metallocorroles;
D O I
10.1002/adsc.200303145
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Metallocorroles, in particular those containing chromium, manganese, and iron, have been found to be efficient catalysts for oxidation reactions. This review deals with work on hydrocarbon oxidations after the 1999 advance made in corrole synthesis that sparked the Technion-Caltech collaborative program.
引用
收藏
页码:165 / 170
页数:6
相关论文
共 52 条
[1]   Synthesis of the first superstructured chiral corrole [J].
Andrioletti, B ;
Rose, E .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (06) :715-716
[2]   High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole [J].
Bendix, J ;
Gray, HB ;
Golubkov, G ;
Gross, Z .
CHEMICAL COMMUNICATIONS, 2000, (19) :1957-1958
[3]   CHROMIUM(V) OXO COMPLEXES OF MACROCYCLIC TETRAAMIDO-N LIGANDS TAILORED FOR HIGHLY OXIDIZED MIDDLE TRANSITION-METAL COMPLEXES - A NEW O-18-LABELING REAGENT AND A STRUCTURE WITH 4 NONPLANAR AMIDES [J].
COLLINS, TJ ;
SLEBODNICK, C ;
UFFELMAN, ES .
INORGANIC CHEMISTRY, 1990, 29 (18) :3433-3436
[4]   Multiple active oxidants in competitive epoxidations catalyzed by porphyrins and corroles [J].
Collman, JP ;
Zeng, L ;
Decréau, RA .
CHEMICAL COMMUNICATIONS, 2003, (24) :2974-2975
[5]  
de Visser SP, 2001, CHEM-EUR J, V7, P4954, DOI 10.1002/1521-3765(20011119)7:22<4954::AID-CHEM4954>3.0.CO
[6]  
2-U
[7]   Multi-state epoxidation of ethene by cytochrome P450: A quantum chemical study [J].
de Visser, SP ;
Ogliaro, F ;
Harris, N ;
Shaik, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (13) :3037-3047
[8]  
Eikey RA, 2002, ANGEW CHEM INT EDIT, V41, P3592
[9]  
Erlen C., 2000, PORPHYRIN HDB, V2, P233
[10]   Chromium(V) and chromium(VI) nitrido complexes of tris(pentafluorophenyl)corrole [J].
Golubkov, G ;
Gross, Z .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) :4507-4510