Revisited structures of dense and dilute stage II lithium-graphite intercalation compounds

被引：108

作者：

Billaud, D ^{[1
]}

Henry, FX ^{[1
]}

Lelaurain, M ^{[1
]}

Willmann, P ^{[1
]}

机构：

[1] CTR NATL ETUD SPATIALES,F-31055 TOULOUSE,FRANCE

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1996年 / 57卷 / 6-8期

关键词：

X-ray diffraction; crystal structure;

D O I：

10.1016/0022-3697(95)00348-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical intercalation of unsolvated lithium into pyrographite has been carried out in LiClO4-ethylene carbonate electrolyte. Pure phases have been isolated and characterized by X-ray diffraction studies. The orientated texture of pyrographite has allowed the study of the different families of Bragg reflections (00l, hk0, hkl) especially for stage I LiC6, 3D stage II LiC12 and dilute stage II 'LiC18' compounds. Experimental data and some theoretical models have been compared.

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页码：775 / 781

页数：7

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