Pd-PANI: preparation and catalytic properties

被引：21

作者：

Drelinkiewicz, A

Hasik, M

Kloc, M

机构：

[1] Jagiellonian Univ, Dept Chem, PL-30060 Krakow, Poland

[2] Acad Min & Met, Dept Mat Sci & Ceram, PL-30059 Krakow, Poland

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

polyaniline and derivatives; scanning electron microscopy; X-ray diffraction; IR spectroscopy;

D O I：

10.1016/S0379-6779(98)00997-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

PANI base was doped in PdCl2 aqueous solutions of low acidity containing predominantly electrically neutral [PdCl2(H2O)(2)] complexes. Under these conditions partial (80%) reduction of Pd2+ to Pd-0 took place. Pd-0 created in this way was present in the form of crystalline particles (XRD, SEM). Pd-PANI exhibited catalytic activity in the liquid phase 2-ethylanthraquinone hydrogenation. The rate and the selectivity of hydrogenation depended on the Pd-0 amount in catalysts.

引用

页码：1307 / 1308

页数：2

共 8 条

[1]

CAO Y, 1989, POLYMER, V30, P230

[2] KINETIC ASPECTS IN THE SELECTIVITY OF DEEP HYDROGENATION OF 2-ETHYLANTHRAQUINONE OVER PD/SIO2 [J].