Synthesis and characterization of novel chiral sulfonato-salen-manganese(III) complex in a zinc-aluminium LDH host

被引：94

作者：

Bhattacharjee, S ^{[1
]}

Anderson, JA ^{[1
]}

机构：

[1] Univ Dundee, Div Phys & Inorgan Chem, Surface Chem & Catalysis Grp, Dundee DD1 4HN, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b315325h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)(6.02)] [Mn](0.19)[C6H5COO](0.48).2H(2)O, where {[Mn] = chiral sulfonato-salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into Zn-II-Al-III layered double hydroxide host), has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.

引用

收藏

页码：554 / 555

页数：2

相关论文

共 21 条

[1] WATER-SOLUBLE COBALT(II) COMPLEXES OF NN'-SUBSTITUTED BIS(SALICYLALDIMINE-5-SULPHONIC ACIDS) - OXYGEN-CARRYING PROPERTIES AND CONVERSION INTO COBALT(III) ORGANO-METALLIC COMPOUNDS [J].

BERRY, KJ ;

MOYA, F ;

MURRAY, KS ;

VANDENBERGEN, AMB ;

WEST, BO .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (01) :109-116

[2] STUDIES ON SINGLET OXYGEN IN AQUEOUS-SOLUTION .2. WATER-SOLUBLE SQUARE-PLANAR NICKEL-COMPLEXES AS QUENCHERS [J].

BOTSIVALI, M ;

EVANS, DF ;

MISSEN, PH ;

UPTON, MW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06) :1147-1149

[3] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

[4] INTERCALATION OF [(MOO2)-O-VI(O2CC(S)PH(2))(2)](2-) IN A ZN(II)-AL(III) LAYERED DOUBLE HYDROXIDE HOST - A STRATEGY FOR THE HETEROGENEOUS CATALYSIS OF THE AIR OXIDATION OF THIOLS [J].

CERVILLA, A ;

CORMA, A ;

FORNES, V ;

LLOPIS, E ;

PALANCA, P ;

REY, F ;

RIBERA, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (04) :1595-1596

[5] MODEL REACTIONS OF MOLYBDO-REDUCTASE - A NOVEL AND HIGHLY EFFICIENT REDUCTION OF NITROBENZENE TO ANILINE CATALYZED BY A MOLYBDENUM-MEDIATED OXYGEN-ATOM TRANSFER-REACTION [J].

CERVILLA, A ;

CORMA, A ;

FORNES, V ;

LLOPIS, E ;

PEREZ, F ;

REY, F ;

RIBERA, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (25) :6781-6782

[6] Silica gel anchored chiral Mn(III)salen complexes for enantioselective epoxidation of unfunctionalised olefins [J].

Choudary, BM ;

Chowdari, NS ;

Kantam, ML ;

Santhi, PL .

CATALYSIS LETTERS, 2001, 76 (3-4) :213-218

[7] Catalytic asymmetric dihydroxylation of olefins with reusable OsO42- on ion-exchangers:: The scope and reactivity using various cooxidants [J].

Choudary, BM ;

Chowdari, NS ;

Jyothi, K ;

Kantam, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (19) :5341-5349

[8] Structural studies of polyoxometalate-anion-pillared layered double hydroxides [J].

Evans, J ;

Pillinger, M ;

Zhang, JJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (14) :2963-2974

[9] Clay-supported non-chiral and chiral Mn(salen) complexes as catalysts for olefin epoxidation [J].

Fraile, JM ;

Garcia, JI ;

Massam, J ;

Mayoral, JA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 136 (01) :47-57

[10]

Holderich W. F., 2002, CATALYSIS, V16, P43