•NO2-Mediated meso-Hydroxylation of Iron(III) Porphyrin

被引：38

作者：

Abhilash, G. J. ^{[1
]}

Bhuyan, Jagannath ^{[1
]}

Singh, Pinky ^{[1
]}

Maji, Suman ^{[1
]}

Pal, Kuntal ^{[1
]}

Sarkar, Sabyasachi ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 05期

关键词：

MOLECULAR-STRUCTURE; HEME DEGRADATION; COMPLEXES; CHEMISTRY; ISOPORPHYRIN; OXOPHLORINS; DIOXYGEN; ABSENCE;

D O I：

10.1021/ic800864w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(NO2)-N-center dot generated from (NO)-N-center dot and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.

引用

页码：1790 / +

页数：4

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