A new rhodamine-based chemosensor exhibiting selective FeIII-amplified fluorescence

被引:464
作者
Xiang, Y [1 ]
Tong, AJ [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
D O I
10.1021/ol060001h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new fluorescent probe 3 was synthesized, and it exhibited high selectivity for Fe-III over other commonly coexistent metal ions in both ethanol and water. Upon the addition of Fe-III, the spirocyclic ring of 3 was opened and a significant enhancement of visible color and fluorescence in the range of 500-600 nm was observed.
引用
收藏
页码:1549 / 1552
页数:4
相关论文
共 26 条
[1]   Iron metabolism [J].
Aisen, P ;
Wessling-Resnick, M ;
Leibold, EA .
CURRENT OPINION IN CHEMICAL BIOLOGY, 1999, 3 (02) :200-206
[2]   A ratiometric fluorescence probe for selective visual sensing of Zn2+ [J].
Ajayaghosh, A ;
Carol, P ;
Sreejith, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :14962-14963
[3]   STRUCTURE OF RED AND ORANGE FLUORESCEIN [J].
ANTHONI, U ;
CHRISTOPHERSEN, C ;
NIELSEN, PH ;
PUSCHL, A ;
SCHAUMBURG, K .
STRUCTURAL CHEMISTRY, 1995, 6 (03) :161-165
[4]   On the development of sensor molecules that display FeIII-amplified fluorescence [J].
Bricks, JL ;
Kovalchuk, A ;
Trieflinger, C ;
Nofz, M ;
Büschel, M ;
Tolmachev, AI ;
Daub, J ;
Rurack, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13522-13529
[5]   Luminescent sensors and switches in the early 21st century [J].
Callan, JF ;
de Silva, AP ;
Magri, DC .
TETRAHEDRON, 2005, 61 (36) :8551-8588
[6]   A highly selective fluorescent chemosensor for lead ions [J].
Chen, CT ;
Huang, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6246-6247
[7]  
Connors K. A., 1987, BINDING CONSTANTS ME
[8]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[9]   Complex ions. II. The stability and activity coefficients of the silver-ammonia ion [J].
Derr, PF ;
Stockdale, RM ;
Vosburgh, WC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :2670-2674
[10]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387