Thiophene separation from aliphatic hydrocarbons using the 1-ethyl-3-methylimidazolium ethylsulfate ionic liquid

被引:108
作者
Alonso, Luisa [1 ]
Arce, Alberto [1 ]
Francisco, Maria [1 ]
Soto, Ana [1 ]
机构
[1] Univ Santiago de Compostela, Dept Chem Engn, E-15782 Santiago De Compostela, Spain
关键词
extraction; LLE; thiophene; alkane; C(2)mim][EtSO4;
D O I
10.1016/j.fluid.2008.06.012
中图分类号
O414.1 [热力学];
学科分类号
摘要
The ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate has been tested as solvent for the separation of thiophene from aliphatic hydrocarbons. Liquid-liquid equilibrium data have been determined for ternary systems containing the ionic liquid, thiophene and C-6, C-7, C-12 or C-16, alkanes at T = 298.15 K. The performance of the ionic liquid as solvent in such systems has been evaluated. The experimental data were correlated using the NRTL and UNIQUAC equations, and the binary interaction parameters have been reported. The phase diagrams for the ternary mixtures including both the experimental and calculated tie-lines have been presented. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:97 / 102
页数:6
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