Entanglement of protons in organic molecules: An attosecond neutron scattering study of C-H bond breaking

被引:42
作者
Chatzidimitriou-Dreismann, CA [1 ]
Abdul-Redah, T [1 ]
Kolaric, B [1 ]
机构
[1] Tech Univ Berlin, Stranski Lab, Inst Chem, D-10623 Berlin, Germany
关键词
D O I
10.1021/ja004186d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Interactions between adjacent particles of condensed phases can lead to quantum correlation phenomena. like quantum interference, entanglement, delocalization, and "Schrodinger's cat" states. Such correlations are theoretically expected to be extremely short-lived because of environmental disturbances. Here, we present experimental evidence for quantum entanglement between well localized protons of C-H bonds of 2-isobutoxyethanol dissolved in D2O. The applied experimental method is neutron Compton scattering (NCS), which has a characteristic time window in the subfemtosecond time range. Our NCS results reveal that, in the subfemtosecond time scale, the measured cross-section density, and thus, in simple terms, the effectively present concentration, of the H atoms is "anomalously" reduced by similar to 20%. Affecting the microdynamics of protons of covalent C-H bonds, this novel effect may have a broad range of chemical and biological applications.
引用
收藏
页码:11945 / 11951
页数:7
相关论文
共 37 条
  • [1] Deconstructing decoherence
    Anglin, JR
    Paz, JP
    Zurek, WH
    [J]. PHYSICAL REVIEW A, 1997, 55 (06) : 4041 - 4053
  • [2] [Anonymous], 2009, Quantum computation and quantum information, DOI DOI 10.1119/1.1463744
  • [3] [Anonymous], 1996, DECOHERENCE APPEARAN
  • [4] Bell J. S., 1964, Physics Physique Fizika, V1, P195, DOI [DOI 10.1103/PHYSICSPHYSIQUEFIZIKA.1.195, 10.1103/Physics-PhysiqueFizika.1.195]
  • [5] Bohm A., 1993, QUANTUM MECH FDN APP
  • [6] BOUWMEESTER D, 2000, PHYSICS QUANTUM INFO
  • [7] CHATZIDIMITRIOU.C, 2000, ISIS 2000 RUTHERFORD, P58
  • [8] CHATZIDIMITRIOU.CA, IN PRESS J ALLOYS CO
  • [9] Sub-femtosecond dynamics and dissociation of C-H bonds in the condensed phase: Effects of entangled protonic states
    Chatzidimitriou-Dreismann, CA
    Abdul-Redah, T
    Sperling, J
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (07) : 2784 - 2792
  • [10] Comment on "Precision neutron interferometric search for evidence of nuclear quantum entanglement in liquid H2O-D2O mixtures"
    Chatzidimitriou-Dreismann, CA
    Redah, TA
    Streffer, RMF
    Hessmo, B
    [J]. PHYSICAL REVIEW LETTERS, 2000, 84 (09) : 2036 - 2036