Direct, high-yield conversion of cellulose into biofuel

被引:463
作者
Mascal, Mark [1 ]
Nikitin, Edward B.
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
biofuels; carbohydrates; cellulose; furans; sustainable chemistry;
D O I
10.1002/anie.200801594
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Fueling up with furans: Cellulose can be converted into furanic biofuels in unprecedented yields using an inexpensive, simple process involving concurrent hydrolysis, dehydration, and chlorine substitution reactions coupled with continuous extraction into an organic phase (see scheme). Furanic ethers, such as those that can be derived from the products above, are known diesel additives. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7924 / 7926
页数:3
相关论文
共 24 条
[1]   Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].
Chheda, Juben N. ;
Huber, George W. ;
Dumesic, James A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183
[2]   Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides [J].
Chheda, Juben N. ;
Roman-Leshkov, Yuriy ;
Dumesic, James A. .
GREEN CHEMISTRY, 2007, 9 (04) :342-350
[3]   Identifying new volatile compounds in toasted oak [J].
Cutzach, I ;
Chatonnet, P ;
Henry, R ;
Dubourdieu, D .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (04) :1663-1667
[4]  
DeMan JM, 1999, PRINCIPLES FOOD CHEM
[5]  
Dörfler J, 2007, ZUCKERINDUSTRIE, V132, P694
[6]   Ethanol can contribute to energy and environmental goals [J].
Farrell, AE ;
Plevin, RJ ;
Turner, BT ;
Jones, AD ;
O'Hare, M ;
Kammen, DM .
SCIENCE, 2006, 311 (5760) :506-508
[7]   Derivatives of methylfurfural [J].
Fenton, HJH ;
Gostling, M .
JOURNAL OF THE CHEMICAL SOCIETY, 1901, 79 :807-816
[8]  
HAMADA K, 1982, Patent No. 1834950
[9]   Ethanol's energy return on investment: A survey of the literature 1990 - Present [J].
Hammerschlag, R .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (06) :1744-1750
[10]   The conversion of sucrose into furan compounds. Part I. 5-hydroxymethylfurfuraldehyde and some derivatives. [J].
Haworth, WN ;
Jones, WGM .
JOURNAL OF THE CHEMICAL SOCIETY, 1944, :667-670