Femtosecond chemically activated reactions: Concept of nonstatistical activation at high thermal energies

被引：37

作者：

Kim, SK ^{[1
]}

Guo, J ^{[1
]}

Baskin, JS ^{[1
]}

Zewail, AH ^{[1
]}

机构：

[1] CALTECH,ARTHUR AMOS NOYES LAB CHEM PHYS,PASADENA,CA 91125

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 22期

关键词：

D O I：

10.1021/jp961066c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Femtosecond chemical activation of reactions at very high thermal energies, much above the bond energy, is developed in this report. We address the concept of nonstatistical dynamics al such high energies. The approach offers a new direction for probing the dynamics of reactions in their ground state with unique activation, collision-free, and temporally and spatially defined.

引用

页码：9202 / 9205

页数：4

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