Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass

被引:867
作者
Alonso, David Martin [1 ]
Wettstein, Stephanie G. [2 ]
Dumesic, James A. [1 ]
机构
[1] Univ Wisconsin, Dept Biol & Chem Engn, Madison, WI 53706 USA
[2] Montana State Univ, Dept Biol & Chem Engn, Bozeman, MT 59715 USA
关键词
ACID-CATALYZED CONVERSION; LEVULINIC ACID; ETHYL LEVULINATE; SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYSTS; FURFURYL ALCOHOL; CARBON-DIOXIDE; CELLULOSE; GLUCOSE; LIQUID;
D O I
10.1039/c3gc37065h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lignocellulosic biomass typically contains more than 50 wt% sugars that can be upgraded to valuable platform molecules, such as levulinic acid (LA) and gamma-valerolactone (GVL). This article focuses on upgrading GVL produced from lignocellulosic biomass to various chemicals and fuels, such as polymers, fuel additives, and jet fuel. We also review the use of GVL as a solvent for biomass processing, which led to significant improvements in product yields and a more simplified process for producing biomass-derived chemicals such as LA, furfural, and hydroxymethylfurfural.
引用
收藏
页码:584 / 595
页数:12
相关论文
共 123 条
[1]   Tandem isomerization-lactonization of olefinic fatty acids using the Lewis acidic ionic liquid, choline chloride•2ZnCl2 [J].
Akula, Shivaraju ;
Kumar, Pandari Phani ;
Prasad, Rachapudi B. N. ;
Kanjilal, Sanjit .
TETRAHEDRON LETTERS, 2012, 53 (27) :3471-3473
[2]   Direct conversion of cellulose to levulinic acid and gamma-valerolactone using solid acid catalysts [J].
Alonso, David Martin ;
Gallo, Jean Marcel R. ;
Mellmer, Max A. ;
Wettstein, Stephanie G. ;
Dumesic, James A. .
CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (04) :927-931
[3]  
Alonso DM, 2013, ENERG ENVIRON SCI, V6, P76, DOI [10.1039/c2ee23617f, 10.1039/C2EE23617F]
[4]   Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents [J].
Alonso, David Martin ;
Wettstein, Stephanie G. ;
Bond, Jesse Q. ;
Root, Thatcher W. ;
Dumesic, James A. .
CHEMSUSCHEM, 2011, 4 (08) :1078-1081
[5]   Catalytic conversion of biomass to biofuels [J].
Alonso, David Martin ;
Bond, Jesse Q. ;
Dumesic, James A. .
GREEN CHEMISTRY, 2010, 12 (09) :1493-1513
[6]   Production of liquid hydrocarbon transportation fuels by oligomerization of biomass-derived C9 alkenes [J].
Alonso, David Martin ;
Bond, Jesse Q. ;
Serrano-Ruiz, Juan Carlos ;
Dumesic, James A. .
GREEN CHEMISTRY, 2010, 12 (06) :992-999
[7]  
[Anonymous], 2008, [No title captured], Patent No. [2008142127, WO 2008142127A1.]
[8]  
[Anonymous], 2005, [No title captured]
[9]   Current alternative engine fuels [J].
Balat, M .
ENERGY SOURCES, 2005, 27 (06) :569-577
[10]  
Beller M., 1996, APPL HOMOGENEOUS CAT