Investigation of dye-matrix interactions in sol-gel derived hybrid organic-inorganic nanocomposites

被引：9

作者：

Guermeur, C ^{[1
]}

Sanchez, C ^{[1
]}

Schaudel, B ^{[1
]}

Nakatani, K ^{[1
]}

Delaire, JA ^{[1
]}

DelMonte, F ^{[1
]}

Levy, D ^{[1
]}

机构：

[1] CORNING SA,CTR RECH FONTAINEBLEAU,F-77210 AVON,FRANCE

来源：

SOL-GEL OPTICS IV | 1997年 / 3136卷

关键词：

organic-inorganic hybrids; sol-gel; photochromic dyes; porphyrins; dye-matrix interactions; transition metal;

D O I：

10.1117/12.284116

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Several dyes such as a spiropyran, a spirooxazine and two tetraarylporphyrins have been incorporated inside hybrid organic-inorganic matrices synthesized through the acid hydrolysis of dimethyldiethoxysilane and zirconium n-propoxide. These matrices are nanocomposites with well defined hydrophilic (zirconium oxopolymer nodules) and hydrophobic (polydimthylsiloxane chains) domains. As a consequence, they are good candidates to investigate dye-matrix interactions in matrices containing transition metal. These interactions are shown to occur through hydrogen bonds, covalent bonds or Lewis acid-base type bonds. They strongly modify the optical response of the dyes (absorption-emission spectra, lifetime, kinetics..).

引用

页码：10 / 19

页数：10