Electrocatalytic performances of Ni/SDC anodes fabricated with EPD techniques for direct oxidation of CH4 in solid oxide fuel cells

被引：15

作者：

Asamoto, Makiko ^{[1
]}

Miyake, Shinji ^{[1
]}

Itagaki, Yoshiteru ^{[1
]}

Sadaoka, Yoshihiko ^{[1
]}

Yahiro, Hidenori ^{[1
]}

机构：

[1] Ehime Univ, Grad Sch Sci & Engn, Dept Mat Sci & Biotechnol, Matsuyama, Ehime 7908577, Japan

来源：

CATALYSIS TODAY | 2008年 / 139卷 / 1-2期

关键词：

Solid oxide fuel cell; Nickel anode; Samarium-doped ceria; Electrophoretic deposition; Direct oxidation of CH4;

D O I：

10.1016/j.cattod.2008.08.027

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The electrochemical performances and the morphologies of Ni/SDC anodes fabricated by EPD technique were investigated for direct oxidation of dry CH4 in solid oxide fuel cells (SOFCs). Ni/SDC(EPD) anode with both 20 wt% of Ni content and 20 mu m of thickness exhibited the lowest overpotential and the highest maximum power density for dry CH4-air SOFC at 973 K. The power density of the cell with Ni/SDC(EPD) anode was higher than that with Ni/SDC fabricated by a conventional slurry coating method. It was found that Ni/SDC(EPD) anode having dense structure suppressed carbon deposition and exhibited a stable cell operation in SOFC using dry CH4. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：77 / 81

页数：5

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