Oxidative nucleophilic substitution of hydrogen in nitrobenzene with 2-phenylpropionitrile carbanion and potassium permanganate oxidant

被引：15

作者：

Makosza, M

Stalinski, K

Klepka, C

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000837

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The carbanion of 2-phenylpropionitrile adds to nitrobenzene in the p-position in liquid ammonia to give the relative stable sigma(H)-adduct which is oxidised with KMnO4 to 2-phenyl-2-(4-nitrophenyl)propionitrile; the relationships of rates of various reactions in these systems are estimated.

引用

页码：837 / 838

页数：2

共 7 条

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[5] REACTIVITY OF NAPHTHYRIDINES TOWARD NITROGEN NUCLEOPHILES
VANDERPLAS, HC
WOZNIAK, M
VANDENHAAK, HJW
[J]. ADVANCES IN HETEROCYCLIC CHEMISTRY, 1983, 33 : 95 - 146
[6] VANDERPLAS HC, 1986, CROAT CHEM ACTA, V59, P33
[7] [No title captured]

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