The study of novel Fe3O4@γ-Fe2O3 core/shell nanomaterials with improved properties

被引:118
作者
Gao, Qian [1 ,2 ]
Chen, Fenghua [1 ,2 ]
Zhang, Jilin [1 ]
Hong, Guangyan [1 ]
Ni, Jiazuan [1 ]
Wei, Xiao [3 ]
Wang, Dejun [3 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Applicat Rare Earth Resources, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
关键词
Fe3O4@gamma-Fe2O3 core/shell nanomaterials; Calcine; Stability; Magnetic property; Photovoltage response; FEPT NANOPARTICLES; FE3O4; TISSUE;
D O I
10.1016/j.jmmm.2008.10.022
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The surface structure of the iron oxide nanoparticles obtained by the co-precipitation method has been investigated, and a thin layer of alpha-FeOOH absorbed on surface of the nanoparticle is confirmed by analyses of Fourier transform infrared (FTIR), X-ray photoelectron spectra (XPS) and surface photovoltage spectroscopy (SPS). After annealed at 400 degrees C, the alpha-FeOOH can be converted to gamma-Fe2O3. The simple-annealed procedure resulted in the formation of Fe3O4@gamma-Fe2O3 core/shell structure with improved stability and a higher magnetic saturation value, and also the simple method can be used to obtain core/shell structure in other similar system. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1052 / 1057
页数:6
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