A stereocomplex of poly(lactide)s with chain end modification: simultaneous resistances to melting and thermal decomposition

被引：40

作者：

Ajiro, Hiroharu ^{[1
,2
]}

Hsiao, Yi-Ju ^{[1
]}

Tran Hang Thi ^{[3
]}

Fujiwara, Tomoko ^{[4
]}

Akashi, Mitsuru ^{[1
,2
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Ctr Adv Med Engn & Informat, Suita, Osaka 565, Japan

[3] Viet Tri Univ Ind, Minist Ind & Trade, Fac Chem Technol, Phu Tho, Vietnam

[4] Univ Memphis, Dept Chem, Memphis, TN 38152 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 68期

关键词：

MECHANICAL-PROPERTIES; BLOCK-COPOLYMERS; RENEWABLE RESOURCES; METHYL-METHACRYLATE; GRAFT-COPOLYMERS; L-LACTIDE; POLYLACTIDE; POLYMERS; ACID; POLYMERIZATION;

D O I：

10.1039/c2cc33589a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The simultaneous improvement of the melting temperature (T-m = 224 degrees C) and the decomposition temperature (T-10 = 359 degrees C) of poly(lactide)s was achieved by the stereocomplex formation of poly(L-lactide) and poly(D-lactide) with bio-based aromatic groups at both initiating and terminating chain ends.

引用

页码：8478 / 8480

页数：3

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