Stereoselective synthesis of three-membered ring compounds via ylide routes

被引：83

作者：

Dai, LX ^{[1
]}

Hou, XL ^{[1
]}

Zhou, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

来源：

PURE AND APPLIED CHEMISTRY | 1999年 / 71卷 / 03期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1351/pac199971030369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three types of small ring compounds (epoxides, aziridines and cyclopropanes) can be synthesized stereoselectively via ylide route. Among them, the stereochemistry of vinyloxiranes, vinylaziridines, cyclopropylesters, amides and ketones can be tuned by the choice of reaction conditions and ylides with varying heteroatoms and ligands. Optically active epoxides and acetylenylaziridines can be prepared via camphor-derived chiral sulfonium ylide routes.

引用

页码：369 / 376

页数：8

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