Synthesis of an oligomer-supported calix[4]arene and selective extraction of Li+

被引：32

作者：

Yilmaz, M ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, TR-42079 Konya, Turkey

来源：

REACTIVE & FUNCTIONAL POLYMERS | 1999年 / 40卷 / 02期

关键词：

polymeric calix[4]arene; calix[4]arene triester; selective metal extraction; Li+ complexation;

D O I：

10.1016/S1381-5148(98)00025-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

To prepare a structure with a count of more than one p-tert-butylcalix[4]arene triketon unit, oligomer (3) was reacted with 25,26-diacetonyoxy-5,11,17,23-tetra-tert-butyl-26-28-dihydroxycalix[4]arene (2) and compound (4) was treated with chloro-acetone to obtain calix[il]arene units containing triketon groups. It was found that the polymeric calix[4]arene was selective to extract Li+ from an aqueous solution which contained Li+, Na+, K+, Ag+, Co2+, Ni2+, CU2+ and Cd2+. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：129 / 133

页数：5

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