Thiophene-linked polyphenylquinoxaline: A new electron transport conjugated polymer for electroluminescent devices

被引：163

作者：

Cui, YT ^{[1
]}

Zhang, XJ ^{[1
]}

Jenekhe, SA ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem Engn, Rochester, NY 14627 USA

来源：

MACROMOLECULES | 1999年 / 32卷 / 11期

关键词：

D O I：

10.1021/ma9901994

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New thiophene-linked conjugated polynoxaline PTQx and oligoquinoxaline TQx were synthesized and characterized. Comparison of their electronic absorption spectra revealed the dominant role of intramolecular charge transfer in their electronic structures and properties. PTQx exhibited a reversible electrochemical reduction and high electron affinity and ionization potential that make it an attractive n-type conjugated polymer. Evaluation of PTQx as an electron transport material for PPV-based light-emitting devices showed that it was far superior to previous electron transport materials.

引用

页码：3824 / 3826

页数：3

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