Effect of ZrO2 incorporation and calcination temperature on the photocatalytic activity of commercial TiO2 for salicylic acid and Cr(VI) photodegradation

被引：68

作者：

Colón, G ^{[1
]}

Hidalgo, MC ^{[1
]}

Navío, JA ^{[1
]}

机构：

[1] Univ Sevilla, CSIC, Ctr Invest Cient Isla de la Cartuja, Inst Ciencia Mat, Seville 41092, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 2002年 / 231卷 / 1-2期

关键词：

ZrO2; TiO2; heterogeneous photocatalysis; salicylic acid; photooxidation; Cr(VI); photoreduction;

D O I：

10.1016/S0926-860X(02)00051-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

ZrO2-TiO2 system was prepared by sol-gel method, by precipitating the ZrOCl(2)(.)8H(2)O precursor at basic pH with TiO2 Degussa P25 and Hombikat UV-tOO, Catalyst has been calcined at two different temperatures and widely characterised (BET, XRD, DR/UV-VIS, XPS and TENVSEM). Certain structural and morphological differences have been found. These results will be very useful for the lately photocatalytic study of these materials for salicylic acid photooxidation and Cr(VI) photoreduction. Different photocatalytic behaviour has been found for the two different TiO2 upon ZrO2 incorporation and calcinations temperature. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：185 / 199

页数：15

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