A ppb-level NO2 gas sensor using coloration reactions in porous glass

被引:38
作者
Tanaka, T [1 ]
Guilleux, A [1 ]
Ohyama, T [1 ]
Maruo, YY [1 ]
Hayashi, T [1 ]
机构
[1] NTT, Integrated Informat & Energy Syst Labs, Musashino, Tokyo 1800012, Japan
关键词
NO2; porous glass; coloration reaction; UV-visible absorption;
D O I
10.1016/S0925-4005(99)00185-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Coloration reactions for NO2 detection were demonstrated to occur in the pores of porous glass. Porous glass chips impregnated with a new combination of coupling reagents (sulfanilamide as a diazotizing reagent and N,N-dimethyl-1-naphthylamine as a coupling reagent) showed large absorbance changes after exposure to NO2 in both artificial and actual environments, indicating their applicability to ppb-level NO2 detection. A simple sensor device, consisting of this doped porous glass, a light-emitting diode as a light source, and a photodiode as a detector, can detect hourly changes in ppb-level NO2 concentrations, which has previously been possible only by using large analytical instruments. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:247 / 253
页数:7
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