Low-coordinate (arylimido)vanadium(V) alkyls: Synthesis and reactivity of V(NAr)(CH2Ph)(3) (Ar=C6H3-2,6-Pr(i)2)

被引：69

作者：

Murphy, VJ

Turner, H

机构：

[1] Exxon Chemical Company, Baytown Polymer Center, Baytown, TX 77522

[2] Symyx Technologies, Sunnyvale, CA 94086

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 12期

关键词：

D O I：

10.1021/om970144v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of a series of stable vanadium(V) alkyls have been achieved by the support of arylimido ligation. The (arylimido)vanadium(V) tribenzyl complex: V(NAr)(CH2Ph)(3) (Ar = C6H3-2, 6-Pr-2(i)) has been prepared in high yield by the treatment of V(NAr)Cb THF with PhCH2MgCl. This compound, which represents the first structurally characterized vanadium(V) trialkyl complex, is a valuable synthetic precursor to a series of other vanadium(V) dialkyl derivatives with supporting alkoxide, aryloxide, and amido functionalities.

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页码：2495 / 2497

页数：3

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