Chemical interactions at polymer interfaces:: poly(p-xylylene-α-tetrahydrothiophene-bromide, chloride) on indium-tin-oxide

被引：13

作者：

Andersson, A ^{[1
]}

Kugler, T

Lögdlund, M

Holmes, AB

Li, X

Salaneck, WR

机构：

[1] Linkoping Univ, Dept Phys IFM, S-58183 Linkoping, Sweden

[2] Univ Cambridge, Melville Lab, Cambridge CB2 3RA, England

来源：

SYNTHETIC METALS | 1999年 / 106卷 / 01期

基金：

瑞典研究理事会;

关键词：

poly(p-xylylene-alpha-tetrahydrothiophene-chloride); indium-tin-oxide; thermal elimination reaction; interfacial interactions;

D O I：

10.1016/S0379-6779(99)00055-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Chemical interactions, at the interface between a precursor polymer for poly( p-phenylenevinylene), namely poly( p-xylylene-alpha-tetrahydrothiophene-chloride), and an indium-tin-oxide transparent electrode, are identified using X-ray photoelectron spectroscopy. The HCl eliminated in the conversion process interacts with the surface of the indium-tin-oxide substrate leading to the formation of indium chloride which then diffuses into the polymer. It appears that indium-tin-oxide, or possibly the indium chloride generated at the interface, acts as a catalyst for the thermal elimination reaction. The results show unequivocally that interfacial interactions are of major importance in understanding, and ultimately improving, the performance of polymer-based electro-luminescent devices. (C) 1999 Published by Elsevier Science S.A. All rights reserved.

引用

页码：13 / 17

页数：5

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