Analysis of stereochemical nonrigidity in five-coordinate cyclopentadienylmetal complexes by the structure correlation method

被引：16

作者：

Smith, JM ^{[1
]}

Coville, NJ ^{[1
]}

机构：

[1] UNIV WITWATERSRAND,DEPT CHEM,CTR APPL CHEM & CHEM TECHNOL,ZA-2050 JOHANNESBURG,SOUTH AFRICA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 15期

关键词：

D O I：

10.1021/om960092u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The intramolecular cis/trans isomerization mechanism of solid-state pseudo-five-coordinate complexes of the type CpML(4) was examined by the structure correlation technique, and the data revealed that the mechanism most likely proceeds via a combined Berry-turnstile mechanism.

引用

页码：3388 / 3392

页数：5

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