Broadband femtosecond fluorescence spectroscopy of [Ru(bpy)3]2+

被引：254

作者：

Cannizzo, Andrea ^{[1
]}

van Mourik, Frank ^{[1
]}

Gawelda, Wojciech ^{[1
]}

Zgrablic, Goran ^{[1
]}

Bressler, Christian ^{[1
]}

Chergui, Majed ^{[1
]}

机构：

[1] LSU, EPFL, SB ISIC, FSB BSP,Lab Spect Ultrarapide, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 19期

关键词：

charge transfer; fluorescence; hot emission; intersystem crossing; ruthenium;

D O I：

10.1002/anie.200600125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's sizzling! Femtosecond fluorescence-upconversion studies of aqueous [Ru(bpy)3]2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing (≈ 10 fs) to the triplet state at constant energy (the colors indicate the luminescence intensity). (Graph Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3174 / 3176

页数：3

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