Spectroscopic and photophysical behavior of 2-quinolone as a probe for Bronsted and Lewis add sites in zeolites

被引:4
作者
Kojima, M [1 ]
Odaka, A
Nakajima, T
Kuriyama, Y
机构
[1] Shinshu Univ, Fac Agr, Dept Biosci & Biotechnol, Matsumoto, Nagano 3908621, Japan
[2] Fac Engn, Dept Chem & Mat Engn, Wakasato, Nagano 3808553, Japan
[3] Kitasato Univ, Sch Sci, Dept Chem, Sagamihara, Kanagawa 2288555, Japan
关键词
D O I
10.1246/cl.1999.675
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bronsted and Lewis acid sites in zeolites were characterized by using 2-quinolone as a probe, by means of ultraviolet and infrared absorption spectra, fluorescence decay lifetime, and ESR. The results showed clearer differences in. the acidity of zeolites compared to those determined by casing Hammett indicators. The species observed in the zeolites depended on the acidity, the cavity size, and the amount of 2-quinolone loaded.
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页码:675 / 676
页数:2
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