Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron

被引：335

作者：

Joo, SH ^{[1
]}

Feitz, AJ ^{[1
]}

Waite, TD ^{[1
]}

机构：

[1] Univ New S Wales, Sch Civil & Environm Engn, Sydney, NSW 2052, Australia

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2004年 / 38卷 / 07期

关键词：

D O I：

10.1021/es035157g

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Degradation of the carbothiolate herbicide, molinate, has been investigated in oxic solutions containing nanoscale zero-valent iron particles and found to be effectively degraded by an oxidative pathway. Both ferrous iron and superoxide (or, at pH <4.8, hydroperoxy) radicals appear to be generated on corrosion of the zero-valent iron with resultant production of strongly oxidizing entities capable of degrading the trace contaminant.

引用

页码：2242 / 2247

页数：6

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