A novel synthesis of chiral rotaxanes via covalent bond formation

被引:54
作者
Kameta, N
Hiratani, A
Nagawa, Y
机构
[1] Utsunomiya Univ, Fac Engn, Dept Appl Chem, Utsunomiya, Tochigi 3218585, Japan
[2] Natl Inst Adv Ind Sci & Technol, Nanoarchitect Res Ctr, Tsukuba, Ibaraki 3058562, Japan
关键词
D O I
10.1039/b314744d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral rotaxanes composed of the asymmetric crownophane incorporating two hydroxy groups as a rotor moiety and the asymmetric axis were effectively synthesized via covalent bond formation, i.e. tandem Claisen rearrangement, esterification, and aminolysis.
引用
收藏
页码:466 / 467
页数:2
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