Structures and templating effect in the formation of 2D layered aluminophosphates with Al3P4O163- stoichiometry

被引：73

作者：

Li, JY ^{[1
]}

Yu, JH ^{[1
]}

Yan, WF ^{[1
]}

Xu, YH ^{[1
]}

Xu, WG ^{[1
]}

Qiu, SL ^{[1
]}

Xu, RR ^{[1
]}

机构：

[1] Jilin Univ, Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 09期

关键词：

D O I：

10.1021/cm990289n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structural features of a family of layered aluminophosphates with Al3P4O163- stoichiometry (denoted L-n) have been discussed. Their 2D sheets ase stabilized by protonated organic amines through. H-bonding interactions with certain regularity. The templating ability of various organic amines for the experimental inorganic layers is investigated in terms of the energies of the host-template interactions. Some experimental phenomena, such as the packing sequence of the inorganic layers and the co-templating role of two types of templates on the formation of some structures, can be explained by energy calculation results. Some organic templates that can potentially direct the formation of a given host can be predicted. This further assists in the rational synthesis of 2D layered compounds with specific structures.

引用

页码：2600 / 2606

页数：7

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