Two-dimensional chirality at liquid-solid interfaces

被引：205

作者：

Elemans, Johannes A. A. W.

De Cat, Inge

Xu, Hong

De Feyter, Steven ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Div Mol & Nanomat, B-3001 Heverlee, Belgium

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 03期

关键词：

SELF-ASSEMBLED MONOLAYERS; SCANNING-TUNNELING-MICROSCOPY; ACHIRAL MOLECULES; EXPRESSION; GRAPHITE; CRYSTALS; OLIGO(P-PHENYLENEVINYLENE)S; VISUALIZATION; ENANTIOMERS; DERIVATIVES;

D O I：

10.1039/b800403j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review highlights the formation of chiral molecular patterns at the liquid-solid interface, revealed at the submolecular level with scanning tunnelling microscopy. It is shown that chiral patterns can be formed by both chiral and achiral molecules. The assembly of mixtures of mirror-image-like molecules gets special attention. Finally, non-standard methods to induce surface chirality in achiral systems are discussed.

引用

页码：722 / 736

页数：15

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Barlow SM, 2003, SURF SCI REP, V50, P201, DOI [10.1016/S0167-5729(03)00015-3, 10.1016/s0167-5729(03)00015-3]

[2] Preparation of chiral surfaces from achiral molecules by controlled symmetry breaking [J].