A new microporous MOF material based on Zn(II)-polycarboxylate coordination polymer synthesized with the aid of 1,6-diaminohexane as template

被引：37

作者：

Chandra, Debraj ^{[1
,2
]}

Kasture, Mahesh W. ^{[3
]}

Bhaumik, Asim ^{[1
,2
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata 700032, India

[2] Indian Assoc Cultivat Sci, Ctr Adv Mat, Kolkata 700032, India

[3] Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, India

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2008年 / 116卷 / 1-3期

关键词：

Coordination polymer; Metal-organic framework; Microporous material; Porosity; Zinc complex;

D O I：

10.1016/j.micromeso.2008.04.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new microporous metal-organic framework (MOF) material ZBTEC-1 has been synthesized by designing infinite coordination polymer network formed between Zn(II) and 1,2,4,5-benzenetetracarboxylic acid (BTEC) under solvothermal conditions in the presence of 1,6-diaminohexane (DAH) as a single molecule template. Powder XRD data demonstrate that the ZBTEC-1 material has a new MOF structure. N-2 sorption studies indicated moderately good surface area (306 m(2) g(-1)) with large size micropores (average pore diameter ca. 0.7 nm) and very high pore volume (1.93 ccg(-1)). C-13 solid state MAS-NMR, FT-IR and UV-visible spectroscopic studies showed the presence of BTEC moieties in the framework. TEM and FE-SEM analysis indicated 30-60 nm diameter size microporous spherical particles for the ZBTEC-1 crystallites. This novel MOF material showed good hydrogen adsorption capacity at 77 K, indicating its potential application in hydrogen storage. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：204 / 209

页数：6

共 43 条

[1] Oriented crystallisation on supports and anisotropic mass transport of the metal-organic framework manganese formate [J].

Arnold, Mirko ;

Kortunov, Pavel ;

Jones, Deborah J. ;

Nedellec, Yannig ;

Kaerger, Joerg ;

Caro, Juergen .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (01) :60-64

[2] Isolation and characterization of ZnII and HgII coordination polymers with a designed azo-aromatic ligand:: Identification of micrometer- and nanometer-sized particles [J].

Banerjee, Priyabrata ;

Kar, Soumitra ;

Bhaumik, Asim ;

Lee, Gene-Hsiang ;

Peng, Shie-Ming ;

Goswami, Sreebrata .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (06) :835-845

[3] Photoluminescence behavior of new mesoporous titanium-composites synthesized by using bidentate structure directing agents [J].

Chandra, Debraj ;

Bhaumik, Asim .

MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 101 (03) :348-354

[4] A novel anionic surfactant templating route for synthesizing mesoporous silica with unique structure [J].

Che, S ;

Garcia-Bennett, AE ;

Yokoi, T ;

Sakamoto, K ;

Kunieda, H ;

Terasaki, O ;

Tatsumi, T .

NATURE MATERIALS, 2003, 2 (12) :801-805

[5] Synthesis, structure, and adsorption properties of a three-dimensional porous yttrium-organic coordination network [J].

Chen, Jinxi ;

Chen, Zhenxia ;

Yu, Ting ;

Weng, Linhong ;

Tu, Bo ;

Zhao, Dongyuan .

MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 98 (1-3) :16-20

[6] Carbide-derived nanoporous carbon and novel core-shell nanowires [J].

Chen, XQ ;

Cantrell, DR ;

Kohlhaas, K ;

Stankovich, S ;

Ibers, JA ;

Jaroniec, M ;

Gao, HS ;

Li, XD ;

Ruoff, RS .

CHEMISTRY OF MATERIALS, 2006, 18 (03) :753-758

[7] Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units [J].

Fang, Qian-Rong ;

Zhu, Guang-Shan ;

Xue, Ming ;

Zhang, Qing-Lin ;

Sun, Jin-Yu ;

Guo, Xiao-Dan ;

Qiu, Shi-Lun ;

Xu, Shi-Tao ;

Wang, Ping ;

Wang, De-Jun ;

Wei, Yen .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) :3754-3758

[8] Synthesis of a carbon replica of zeolite Y with large crystallite size [J].

Garsuch, A ;

Klepel, O ;

Sattler, RR ;

Berger, C ;

Gläser, R ;

Weitkamp, J .

CARBON, 2006, 44 (03) :593-596

[9] Guest-dependent spin crossover in a nanoporous molecular framework material [J].

Halder, GJ ;

Kepert, CJ ;

Moubaraki, B ;

Murray, KS ;

Cashion, JD .

SCIENCE, 2002, 298 (5599) :1762-1765

[10] Topological control in heterometallic metal-organic frameworks by anion templating and metalloligand design [J].

Halper, Sara R. ;

Do, Loi ;

Stork, Jay R. ;

Cohen, Seth M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15255-15268

← 1 2 3 4 5 →