Synthesis of poly(methyl methacrylate) stabilized colloidal zero-valence metallic nanoparticles

被引:121
作者
Guo, ZH
Henry, LL
Palshin, V
Podlaha, EJ
机构
[1] Louisiana State Univ, Gordon A & Mary Cain Dept Chem Engn, Baton Rouge, LA 70803 USA
[2] So Univ & A&M Coll, Dept Phys, Baton Rouge, LA 70813 USA
[3] SE Louisiana Univ, Ctr Adv Microstruct & Devices, Baton Rouge, LA 70806 USA
关键词
D O I
10.1039/b515565g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Poly(methyl methacrylate) (PMMA) stabilized colloidal metallic iron nanoparticles without additional surfactant or stabilizer were fabricated by a wet chemical reduction method. The synthesized colloidal iron nanoparticles were found to be stable in tetrahydrofuran (THF) solution and the dried PMMA-Fe nanocomposites were ferromagnetic even at room temperature as illustrated by magnetometer measurement. The particle size increased with the decrease of the initial PMMA concentration and the magnetic properties also depended on the initial PMMA concentration.
引用
收藏
页码:1772 / 1777
页数:6
相关论文
共 61 条
[1]   Magnetic behavior of iron and iron-oxide nanoparticle/polymer composites [J].
Baker, C ;
Shah, SI ;
Hasanain, SK .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2004, 280 (2-3) :412-418
[3]   Possible exploitation of magnetic nanoparticle-cell interaction for biomedical applications [J].
Berry, CC .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (05) :543-547
[4]   Functionalisation of magnetic nanoparticles for applications in biomedicine [J].
Berry, CC ;
Curtis, ASG .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (13) :R198-R206
[5]   SELECTIVE REDUCTIONS .26. LITHIUM TRIETHYLBOROHYDRIDE AS AN EXCEPTIONALLY POWERFUL AND SELECTIVE REDUCING AGENT IN ORGANIC-SYNTHESIS - EXPLORATION OF THE REACTIONS WITH SELECTED ORGANIC-COMPOUNDS CONTAINING REPRESENTATIVE FUNCTIONAL-GROUPS [J].
BROWN, HC ;
KIM, SC ;
KRISHNAMURTHY, S .
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (01) :1-12
[6]   Magnetic nanocomposites:: Preparation and characterization of polymer-coated iron nanoparticles [J].
Burke, NAD ;
Stöver, HDH ;
Dawson, FP .
CHEMISTRY OF MATERIALS, 2002, 14 (11) :4752-4761
[7]   Preparation and characterization of polymer-coated magnetic nanoparticles [J].
Burke, NAD ;
Stöver, HDH ;
Dawson, FP ;
Lavers, JD ;
Jain, PK ;
Oka, H .
IEEE TRANSACTIONS ON MAGNETICS, 2001, 37 (04) :2660-2662
[8]  
CARPENTER EE, 2000, J APPL PHYS, P87
[9]   Production of magnetic nanoparticles in imine polymer matrixes [J].
Castro, C ;
Ramos, J ;
Millán, A ;
González-Calbet, J ;
Palacio, F .
CHEMISTRY OF MATERIALS, 2000, 12 (12) :3681-3688
[10]   MAGNETIC-PROPERTIES OF NANOPHASE COBALT PARTICLES SYNTHESIZED IN INVERSED MICELLES [J].
CHEN, JP ;
SORENSEN, CM ;
KLABUNDE, KJ ;
HADJIPANAYIS, GC .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (10) :6316-6318