Chemical compatibility of (La0.6Ca0.4)(x)Fe(0.8)M(0.2)O(3) with yttria-stabilized zirconia

被引:28
作者
Kindermann, L [1 ]
Das, D [1 ]
Nickel, H [1 ]
Hilpert, K [1 ]
Appel, CC [1 ]
Poulson, FW [1 ]
机构
[1] RES CTR JULICH,INST MAT ENERGY SYST,JULICH,GERMANY
关键词
D O I
10.1149/1.1837474
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
LaFeO3-based perovskites are of interest as cathode material for the development of advanced solid oxide fuel cells operating at temperatures significantly lower than 900 degrees C. The compatibility of the selected materials is necessary to guarantee long-term operation of a solid oxide fuel cell. Systematic investigations on the reactivity between the solid electrolyte yttria-stabilized zirconia (ZrO2 + 8 mole percent Y2O3) and the perovskites (La0.6Ca0.4)(x)Fe(0.8)M(0.2)O(3) (x = 1, 0.9; M = Cr, Mn, Co, Ni) were carried out. The results obtained are discussed.
引用
收藏
页码:717 / 720
页数:4
相关论文
共 14 条
[1]  
HAMMOU A, 1992, ADV ELECTROCHEMICAL, V2, P87
[2]  
ISSACS HS, 1982, J ELECTROCHEM SOC, V129, P436
[3]  
KINDERMANN L, IN PRESS
[4]  
KINDERMANN L, 1994, P 6 IEA WORKSH ADV S, P289
[5]   CERAMIC FUEL-CELLS [J].
MINH, NQ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588
[6]   NONSTOICHIOMETRY, DIFFUSION, AND ELECTRICAL-PROPERTIES OF PEROVSKITE-TYPE OXIDE ELECTRODE MATERIALS [J].
MIZUSAKI, J .
SOLID STATE IONICS, 1992, 52 (1-3) :79-91
[7]  
SINGHAL SC, 1991, 2ND P INT S SOFC ATH, P25
[8]  
STEELE BCH, 1994, P 1 EUR SOL OX FUEL, P375
[9]  
STEINER R, 1972, P 4 INT S FUEL CELLS, P114
[10]  
SYSKAKIS E, 1994, P 2 INT C CER EN APP, P91