A novel triphenylamine-substituted poly(p-phenylenevinylene):: Improved photo- and electroluminescent properties

被引：82

作者：

Pu, YJ

Soma, M

Kido, J ^{[1
]}

Nishide, H

机构：

[1] Waseda Univ, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan

[2] Yamagata Univ, Grad Sch Sci & Engn, Yonezawa, Yamagata 9928510, Japan

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 11期

关键词：

D O I：

10.1021/cm010713w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel triphenylamine-substituted and fully conjugated poly(1,4-phenylenevinylene), poly[5-(4'-(N,N-diphenylamino)-phenyl)-2-(2'-ethylhex-yloxy)-1,4-phenylenevinylene-alt-5-methoxy-2-(2'-ethylhexyloxy)-1,4-phenylenevinylene] was synthesized by Wittig-Horner-type polycondensation. The polymer gave a high photoluminescence efficiency as a film (31%) and a low ionization potential of -5.1 eV. The simple double-layer light-emitting-diode devices of the polymer exhibited a very high luminance of 29 500 cd/m(2) under a low driving voltage (approximate to8 V).

引用

收藏

页码：3817 / +

页数：4

相关论文

共 26 条

[1] New alternating donor-acceptor type conjugated copolymer: Poly[bicarbazolylene-alt-phenylene-bis(cyanovinylene)]. Synthesis and properties [J].

Boucard, V ;

Benazzi, T ;

Ades, D ;

Sauvet, G ;

Siove, A .

POLYMER, 1997, 38 (14) :3697-3703

[2] VISIBLE-LIGHT EMISSION FROM SEMICONDUCTING POLYMER DIODES [J].

BRAUN, D ;

HEEGER, AJ .

APPLIED PHYSICS LETTERS, 1991, 58 (18) :1982-1984

[3] Electroluminescence from silyl-disubstituted PPV derivative [J].

Chu, HY ;

Hwang, DH ;

Do, LM ;

Chang, JH ;

Shim, HK ;

Holmes, AB ;

Zyung, TY .

SYNTHETIC METALS, 1999, 101 (1-3) :216-217

[4] An improved experimental determination of external photoluminescence quantum efficiency [J].

deMello, JC ;

Wittmann, HF ;

Friend, RH .

ADVANCED MATERIALS, 1997, 9 (03) :230-&

[5] MEASUREMENT OF ABSOLUTE PHOTOLUMINESCENCE QUANTUM EFFICIENCIES IN CONJUGATED POLYMERS [J].

GREENHAM, NC ;

SAMUEL, IDW ;

HAYES, GR ;

PHILLIPS, RT ;

KESSENER, YARR ;

MORATTI, SC ;

HOLMES, AB ;

FRIEND, RH .

CHEMICAL PHYSICS LETTERS, 1995, 241 (1-2) :89-96

[6] A new family of highly emissive soluble poly(p-phenylene vinylene) derivatives.: A step toward fully conjugated blue-emitting poly(p-phenylene vinylenes) [J].

Hsieh, BR ;

Yu, Y ;

Forsythe, EW ;

Schaaf, GM ;

Feld, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) :231-232

[7]

KARFT A, 1998, ANGEW CHEM INT EDIT, V37, P402

[8] Electroluminescent poly(arylene ether) containing both hole-transporting and electron-transporting units [J].

Kido, J ;

Harada, G ;

Nagai, K .

CHEMISTRY LETTERS, 1996, (02) :161-162

[9]

KIDO J, 2000, POLYM PREP JPN, V49, P3367

[10] IMINE-BRIDGED PLANAR POLY(P-PHENYLENE) DERIVATIVES FOR MAXIMIZATION OF EXTENDED PI-CONJUGATION - THE COMMON INTERMEDIATE APPROACH [J].

LAMBA, JJS ;

TOUR, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (26) :11723-11736