Activation of molecular oxygen in systems containing methyltrioxorhenium and its derivatives

被引:14
作者
Eager, MD
Espenson, JH [1 ]
机构
[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA
[2] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA
关键词
D O I
10.1021/ic981388q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The activation of molecular oxygen arises from its reaction with a dioxorhenium(V) complex, giving the peroxo complex that rapidly converts phosphine to phosphine oxide.
引用
收藏
页码:2533 / +
页数:4
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