The effect of carbon pore structure on the adsorption of cigarette smoke vapour phase compounds

被引:63
作者
Branton, Peter [1 ]
Lu, An-Hui [2 ]
Schueth, Ferdi [2 ]
机构
[1] British Amer Tobacco, Res & Dev Grp, Southampton SO15 8TL, Hants, England
[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
HYDROGEN-CYANIDE;
D O I
10.1016/j.carbon.2008.12.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The pore size, distribution and volume of activated carbon are extremely important maximizing adsorption of vapours formed during cigarette smoking. Increasing volume leads to an increase in the removal efficiency. Because of the relatively high rates encountered during the smoking process, mesopores appear to be beneficial as transport pores especially in cases where the micropore volume is relatively low and thus the most accessible micropore sites may be rapidly saturated. Film diffusion limitations seem to be present at the very high space velocities encountered in a filter under the conditions of cigarette smoking. The removal efficiency from smoke is approximately inversely proportional to the vapour pressure of the constituents. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1005 / 1011
页数:7
相关论文
共 15 条
[1]  
Baker RR., 1999, Tobacco- Production, Chemistry and Technology Blackwell Science, P398
[2]   Preparation, characterisation and application of metal-doped carbons for hydrogen cyanide removal [J].
Barnes, PA ;
Chinn, MJ ;
Dawson, EA ;
Norman, PR .
ADSORPTION SCIENCE & TECHNOLOGY, 2002, 20 (09) :817-833
[3]   EFFECT OF AGING AND MOISTURE ON THE RETENTION OF HYDROGEN-CYANIDE BY IMPREGNATED ACTIVATED CHARCOALS [J].
BROWN, PN ;
JAYSON, GG ;
THOMPSON, G ;
WILKINSON, MC .
CARBON, 1989, 27 (06) :821-833
[4]   Could charcoal filtration of cigarette smoke reduce smoking-induced disease? A review of the literature [J].
Coggins, Christopher R. E. ;
Gaworski, Charles L. .
REGULATORY TOXICOLOGY AND PHARMACOLOGY, 2008, 50 (03) :359-365
[5]   The changing cigarette, 1950-1995 [J].
Hoffmann, D ;
Hoffmann, I .
JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH, 1997, 50 (04) :307-364
[6]  
*ISO, 1991, 3308 ISO
[7]  
Leffingwell JC., 1999, Tobacco - Production, Chemistry and Technology, P265, DOI DOI 10.13140/2.1.5173.6645
[8]  
Lide DavidR., 2006, CRC HDB CHEM PHYS, V87th, P6
[9]   The characterisation and evaluation of activated carbon in a cigarette filter [J].
Mola, Michele ;
Hallum, Matthew ;
Branton, Peter .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (2-3) :335-341
[10]  
Newsome J., 1965, TOBACCO SCI, V9, P102