Laponite: What is the difference between a gel and a glass?

被引:252
作者
Bonn, D
Kellay, H
Tanaka, H
Wegdam, G
Meunier, J
机构
[1] Ecole Normale Super, Phys Stat Lab, F-75231 Paris 05, France
[2] Univ Bordeaux 1, CPMOH, F-33405 Talence, France
[3] Univ Tokyo, Inst Ind Sci, Minato Ku, Tokyo 106, Japan
[4] Univ Amsterdam, Waals Zeeman Lab, NL-1081 XE Amsterdam, Netherlands
关键词
D O I
10.1021/la990167+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solutions of the synthetic clay Laponite are strongly viscoelastic, even at very low particle concentrations. The formation of a gel, evidenced by the existence of a fractal network, has been invoked in explaining the viscoelasticity. We study the structure and viscosity of Laponite using static light scattering and rheometry. Contrary to previous observations, we find no evidence of a fractal-like organization of the colloidal particles, provided the dispersion is prepared carefully. The results show that there is no relation between the apparent fractal dimension and the viscoelasticity, A possible interpretation of our results is that Laponite solutions form colloidal glasses, rather than gels.
引用
收藏
页码:7534 / 7536
页数:3
相关论文
共 17 条
[1]   COLLOIDAL PROPERTIES OF SYNTHETIC HECTORITE CLAY DISPERSIONS .2. LIGHT AND SMALL-ANGLE NEUTRON-SCATTERING [J].
AVERY, RG ;
RAMSAY, JDF .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 109 (02) :448-454
[2]   Aging of a colloidal "Wigner" glass [J].
Bonn, D ;
Tanaka, H ;
Wegdam, G ;
Kellay, H ;
Meunier, J .
EUROPHYSICS LETTERS, 1999, 45 (01) :52-57
[3]   Statistical model for the structure and gelation of smectite clay suspensions [J].
Dijkstra, M ;
Hansen, JP ;
Madden, PA .
PHYSICAL REVIEW E, 1997, 55 (03) :3044-3053
[4]   Structure and formation of a gel of colloidal disks [J].
Kroon, M ;
Vos, WL ;
Wegdam, GH .
PHYSICAL REVIEW E, 1998, 57 (02) :1962-1970
[5]   Dynamic light scattering studies on the sol-gel transition of a suspension of anisotropic colloidal particles [J].
Kroon, M ;
Wegdam, GH ;
Sprik, R .
PHYSICAL REVIEW E, 1996, 54 (06) :6541-6550
[6]  
Lyklema J., 1993, FUNDAMENTALS COLLOID
[7]   Sol-gel transition of colloidal suspensions of anisotropic particles of laponite [J].
Mourchid, A ;
Delville, A ;
Levitz, P .
FARADAY DISCUSSIONS, 1995, 101 :275-285
[8]   PHASE-DIAGRAM OF COLLOIDAL DISPERSIONS OF ANISOTROPIC CHARGED-PARTICLES - EQUILIBRIUM PROPERTIES, STRUCTURE, AND RHEOLOGY OF LAPONITE SUSPENSIONS [J].
MOURCHID, A ;
DELVILLE, A ;
LAMBARD, J ;
LECOLIER, E ;
LEVITZ, P .
LANGMUIR, 1995, 11 (06) :1942-1950
[9]   Long-term gelation of laponite aqueous dispersions [J].
Mourchid, A ;
Levitz, P .
PHYSICAL REVIEW E, 1998, 57 (05) :R4887-R4890
[10]  
Olphen Hv, 1977, An Introduction to Clay Colloid Chemistry