Porous polyethersulfone hollow fiber membrane in CO2 separation process via membrane contactor - The effect of nonsolvent additives

被引:18
作者
Bakeri, Gholamreza [1 ]
Rezaei-DashtArzhandi, Masoud [2 ]
Ismail, Ahmad Fauzi [2 ]
Matsuura, Takeshi [3 ]
Abdullah, Mohd Sohaimi [2 ]
Cheer, Ng Be [2 ]
机构
[1] Babol Noshirvani Univ Technol, Adv Membrane & Biotechnol Res Ctr, Babol Sar, Iran
[2] Univ Teknol Malaysia, Adv Membrane Technol Res Ctr AMTEC, Skudai 81310, Johor, Malaysia
[3] Univ Ottawa, Dept Chem & Biol Engn, Ottawa, ON K1N 6N5, Canada
关键词
Polyethersulfone; Membrane Contactor; Phase Inversion Promoter; Hollow Fiber Membrane; ULTRAFILTRATION MEMBRANES; POLYETHYLENE-GLYCOL; MASS-TRANSFER; PERFORMANCE; PES; TEMPERATURE; MORPHOLOGY; WATER;
D O I
10.1007/s11814-016-0258-4
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A membrane contactor (MC) is used for natural gas sweetening and wastewater treatment with a membrane that is acting as a separating barrier between two phases, usually liquid and gas. The performance of membrane is governed by parameters such as pore size, porosity, tortuosity and surface hydrophobicity, which can be controlled by a number of methods. Addition of nonsolvents to spinning solution is known to be one of such methods. In this study, the effects of low molecular weight additives as phase inversion promoters on the morphology of polyethersulfone hollow fiber membranes and their performance in gas-liquid MC processes were investigated. It was found that among the six nonsolvent additives under study, addition of water resulted in the highest CO2 flux, by decreasing the thermodynamic stability of polymer solution and maintaining high solvent-nonsolvent exchange rate.
引用
收藏
页码:160 / 169
页数:10
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