Ferromagnetism of the hybrid open framework K[M3(BTC)3]•5H2O (M = Fe, Co) or MIL-45

被引：40

作者：

Riou-Cavellec, M

Albinet, C

Livage, C

Guillou, N

Noguès, A

Grenèche, JM

Férey, G

机构：

[1] Inst Lavoisier, UMR CNRS 8637, F-78035 Versailles, France

[2] Lab LMOV, F-78035 Versailles, France

[3] Univ Maine, Lab Phys Etat Condense, UMR CNRS 6087, F-72085 Le Mans, France

来源：

SOLID STATE SCIENCES | 2002年 / 4卷 / 02期

关键词：

mixed-metal carboxylate; hybrid material; ferromagnetism;

D O I：

10.1016/S1293-2558(01)01225-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MIL-45 or K[M-3(BTC)(3)].5H(2)O (M = Co, Fe) presents a hybrid 3D open structure based on undulating octahedral chains linked by two different trimesate anions. This compound exhibits ferromagnetic behaviour below 10 K for the pure Co phase and 20 K for the mixed-metal (Co, Fe) phase. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

引用

页码：267 / 270

页数：4

共 12 条

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[Anonymous], 1996, SADABS PROGRAM SCALI

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