Hollow polyaniline microspheres with conductive and fluorescent function

被引:67
作者
Zhang, Lijuan
Wang, Meixiang [1 ]
Wei, Yen
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solid Lab, Beijing 100080, Peoples R China
[2] Drexel Univ, Dept Chem, Ctr Adv Polymers & Mat Chem, Philadelphia, PA 19104 USA
关键词
fluorescence; hollow composite spheres; rhodamine B; self-assembly process; template-free method;
D O I
10.1002/marc.200600134
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Salicylic acid doped hollow polyaniline and rhodamine B composite spheres (1.9-3.3 mu m in average diameter) with a high conductivity (approximate to 10(-1) S . cm(-1)) and a strong fluorescence were synthesized by a template-free method. The morphologies, electrical and fluorescent properties of the hollow composite micropheres can be adjusted by changing the content of RhB in the composites opening a simple route to preparing multi-functionalized micro/nano-structures.
引用
收藏
页码:888 / 893
页数:6
相关论文
共 30 条
[1]  
Arshady R., 1999, MICROSPHERES MICROCA, V1, P165
[2]   Raman spectroscopy for the study of polyaniline [J].
Bernard, MC ;
HugotLeGoff, A .
SYNTHETIC METALS, 1997, 85 (1-3) :1145-1146
[3]   CHEMICAL OSCILLATIONS IN ABSORBANCE OF RHODAMINE-B IN SOLVENTS OF LOW DIELECTRIC-CONSTANT [J].
BIGELOW, RW .
JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (01) :88-89
[4]   Vibrational analysis of polyaniline: A model compound approach [J].
Boyer, MI ;
Quillard, S ;
Rebourt, E ;
Louarn, G ;
Buisson, JP ;
Monkman, A ;
Lefrant, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (38) :7382-7392
[5]   Array of nickel nanowires enveloped in polyaniline nanotubules and its magnetic behavior [J].
Cao, HQ ;
Tie, CY ;
Xu, Z ;
Hong, JM ;
Sang, H .
APPLIED PHYSICS LETTERS, 2001, 78 (11) :1592-1594
[6]   COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE [J].
CAO, Y ;
SMITH, P ;
HEEGER, AJ .
SYNTHETIC METALS, 1993, 57 (01) :3514-3519
[7]   POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].
CHIANG, JC ;
MACDIARMID, AG .
SYNTHETIC METALS, 1986, 13 (1-3) :193-205
[8]  
Cochet M, 2000, J RAMAN SPECTROSC, V31, P1041, DOI 10.1002/1097-4555(200012)31:12<1041::AID-JRS641>3.0.CO
[9]  
2-R
[10]  
Heeger AJ, 2001, ANGEW CHEM INT EDIT, V40, P2591, DOI 10.1002/1521-3773(20010716)40:14<2591::AID-ANIE2591>3.0.CO