A novel two-dimensional honeycomb-like bimetallic iron(III)-nickel(II) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2•nH2O (cyclam=1,4,8,11-tetraazacyclodecane)

被引：135

作者：

Colacio, E ^{[1
]}

Domínguez-Vera, JM

Ghazi, M

Kivekäs, R

Lloret, F

Moreno, JM

Stoeckli-Evans, H

机构：

[1] Univ Granada, Fac Ciencias, Dept Quim Inorgan, E-18071 Granada, Spain

[2] Univ Helsinki, Inorgan Chem Lab, Dept Chem, FIN-00014 Helsinki, Finland

[3] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Burjassot, Spain

[4] Univ Neuchatel, Inst Chim, CH-200 Neuchatel, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a902041a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2D honeycomb-like layered iron(III)-nickel(II) cyanide-bridged complex [Ni(cyclam)](3)[Fe(CN)(6)](2). nH(2)O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properties are typical of a metamagnet with H-c = 5000 G, whereas below 3 K a canted structure is formed, leading to a long range ferromagnetic ordering.

引用

页码：987 / 988

页数：2

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