Characteristic length of fuel and oxygen consumption in feed channels of polymer electrolyte fuel cells

被引:25
作者
Kornyshev, AA [1 ]
Kulikovsky, AA [1 ]
机构
[1] Res Ctr Julich, Inst Mat & Proc Energy Syst IWV 3, D-52425 Julich, Germany
关键词
PEMFC; DMFC; channel; feed consumption;
D O I
10.1016/S0013-4686(01)00662-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
How much of feed channels is actually used in a fuel cell? This problem is considered in this paper where we study gas or liquid feed consumption in the feed supplying channels of a polymer electrolyte fuel cell. Simple analytical expressions which define profiles of feed concentration along the channel and expressions for characteristic length of feed consumption are obtained. For typical conditions this length could be as low as several tens of centimeters. The dependence of consumption length on reaction rate parameters and system parameters is discussed. Analytical results are in good agreement with data of simulation, performed specially to verify the validity of the theory. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4389 / 4395
页数:7
相关论文
共 13 条
[1]   A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].
BERNARDI, DM ;
VERBRUGGE, MW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2477-2491
[2]   MATHEMATICAL-MODEL OF A GAS-DIFFUSION ELECTRODE BONDED TO A POLYMER ELECTROLYTE [J].
BERNARDI, DM ;
VERBRUGGE, MW .
AICHE JOURNAL, 1991, 37 (08) :1151-1163
[3]   The current voltage plot of PEM fuel cell with long feed channels [J].
Dohle, H ;
Kornyshev, AA ;
Kulikovsky, AA ;
Mergel, J ;
Stolten, D .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (02) :73-80
[4]   Three-dimensional numerical simulation of straight channel PEM fuel cells [J].
Dutta, S ;
Shimpalee, S ;
Van Zee, JW .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2000, 30 (02) :135-146
[5]   Two-dimensional finite-element method study of the resistance of membranes in polymer electrolyte fuel cells [J].
Futerko, P ;
Hsing, IM .
ELECTROCHIMICA ACTA, 2000, 45 (11) :1741-1751
[6]  
Gottesfeld S, 1997, ADV ELECTROCHEM SCI, V5, P195, DOI DOI 10.1002/9783527616794.CH4
[7]  
IOSELEVICH AS, 2001, FUEL CELLS, V1
[8]   Modeling the cathode compartment of polymer electrolyte fuel cells: Dead and active reaction zones [J].
Kulikovsky, AA ;
Divisek, J ;
Kornyshev, AA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (11) :3981-3991
[9]   Numerical simulation of a new operational regime for a polymer electrolyte fuel cell [J].
Kulikovsky, AA .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (08) :460-466
[10]  
Newman J., 1991, ELECTROCHEMICAL SYST