Third-order nonlinear optical susceptibility of polymers based on carbazole derivatives

被引:10
作者
Fuks, I
Derkowska, B
Sahraoui, B
Niziol, S
Sanetra, J
Bogdal, D
Pielichowski, J
机构
[1] Univ Angers, CNRS, UMR 6136, Lab Prop Opt Mat & Applicat, F-49045 Angers 01, France
[2] WSP Czestochwa, Inst Phys, Czestochowa, Poland
[3] Nicholas Copernicus Univ, Inst Phys, PL-87100 Torun, Poland
[4] Univ Angers, CNRS, UMR 6136, Lab Prop Mat & Applicat, F-49045 Angers 01, France
[5] Univ Min & Met Krakow, Krakow, Poland
[6] Cracow Univ Technol, Krakow, Poland
关键词
D O I
10.1364/JOSAB.19.000089
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The third-order nonlinear optical susceptibility (chi(<3>))of poly(N-vinylcarbazole) (PVK) and two other modified polymers based on carbazole derivatives has been measured by degenerate four-wave mixing at 532 nm in a tetrahydrofuran solution. The polymer exhibits large third-order nonlinear optical susceptibility (chi(<3>)) values. The calculated chi(<3>) value for the copolymer 3-(2-metacryletoxy)carbonyl 7 diethylamin-coumarine (PC1MK), which was obtained by linking 2-(9-carbazolyl)ethyl methacrylate polymer with 3-(2-metacryletoxy)carbonyl 7 diethylamin-coumarine monomer, is approximately 3 times larger than those of poly(3-methoxy-N-vinyl)carbazole and (PVK). (C) 2002 Optical Society of America.
引用
收藏
页码:89 / 93
页数:5
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