Solid state synthesis of coordination compounds from basic metal salts

被引：87

作者：

Adams, Christopher J. ^{[1
]}

Kurawa, Mukhtar A. ^{[1
]}

Lusi, Matteo ^{[1
]}

Orpen, A. Guy ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CRYSTENGCOMM | 2008年 / 10卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b809950b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of the complex salts [H(2)im](2)[MCl4] (H(2)im = imidazolium, M Co, 1; Zn, 2; Cu, 3) and coordination compounds [MCl2(Him)(2)] (M = Co, 4; Zn, 5; Cu, 6) by a range of solid-state and solid-gas reactions is reported. Compounds 4-6 and the related [{MCl2(4,4'-bipy)}(n)] (M = Co, 7; Zn, 8) were prepared by the solid state reactions of metal hydroxide or carbonate salts ( or their equivalent) with the hydrochloride salt of the appropriate ligand (imidazole or 4,4'-bipy).

引用

页码：1790 / 1795

页数：6

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